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of the water in the bowing behavior under thermal cycles. However the nature of the microstylolites needs to be completely analysed, especially if clays are present. Therefore, more studies are necessary to understand completely the anomalous bowing behavior of the Valverde limestone.

       Conclusions

      The boeing potential of eleven varieties of Portuguese limestones were studied. Only one variety (Valverde) show evident bowing, reaching values around 9 mm/m after 91 cycles. This variety is also the only one showing hydric dilatation with values around 0.26 mm/m after 24 hours. Residual strain happens only in wet conditions, with values around 0.25 mm/m.

      Petrographic observations of this variety highlight the presence of disturbed areas with parallel microstylolites. The microstylolites are of an opaque material, probably accumulations of organic material and clays. Both water and heat may cause the opening and offsetting of the microstylolites causing irreversible deformation.

      Further studies are necessary to fully explain this bowing behavior. Meanwhile, this stone should not be used as a cladding material in a humid and warm environment, where bowing behavior can occur more easily.

       References

      Carvalho J., Lisboa V. 2018. Ornamental stone potential areas for land use planning: a case study in a limestone massif from Portugal. Environ Earth Sci 77:206. https://doi.org/10.1007/s12665-018-7382-x.

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      Flügel E. 2004. Microfacies of Carbonate Rocks. Analysis, Interpretation and Application: Germany, Springer, 976 pp.

      Folk R. L. 1962. Spectral subdivision of limestones types. In Ham, W. E. (ed.), Classification of Carbonate Rocks: American Association of Petroleum Geologists, Memoir 1, 62–84.

      Koch A., Siegesmund S. 2002. Bowing of marble panels: on-site damage analysis from the Oeconomicum building at Goettingen (Germany). Geological Society, London, Special Publications 205(1):299–314

      Koch A., Siegesmund S. 2004. The combined effect of moisture and temperature on the anomalous expansion behaviour of marble. Environ Geol 46:350–363

      150Menningen J., Siegesmund S., Lopes L., Martins, R., Sousa, L. 2018. The Estremoz marbles: an updated summary on the geological, mineralogical and rock physical characteristics. Environ Earth Sci 77: 191. https://doi.org/10.1007/s12665-018-7328-3

      Shushakova V., Fuller E. R., Heidelbach F., Mainprice D., Siegesmund S. 2013. Marble decay induced by thermal strains: simulations and experiments. Environ Earth Sci 69(4):1281–1297

      Siegesmund S. 2008. Neue Steine und alte Sorgen—Fassadenplatten aus Naturstein: Sicherheitsrisiken und Sanierungsstrategien. In: H. Venzmer (Hrsg.) 19. Hanseatische Sanierungstage Bauphysik und Bausanierung Heringsdorf 2008, S. 17–27, Beuth Verlag, Berlin.

      Siegesmund S., Dürrast H. 2014. Physical and mechanical properties of the rocks. In: Siegesmund S, Snethlage R (eds) Stone in architecture. Properties, durability, 5th ed. Springer.

      Siegesmund S., Rüdrich J., Koch A. 2008. Marble bowing: comparative studies of three different public building façades. Environ Geol 56(3–4):473–494.

      Siegesmund S., Sousa L., Knell C. 2018. Thermal expansion of granitoids Environ Earth Sci 77: 41. https://doi.org/10.1007/s12665-017-7119-2.

      Siegesmund S., Ullemeyer K., Weiss T., Tschegg E. K. 2000. Physical weathering of marbles caused by anisotropic thermal expansion. Int J Earth Sci 89(1):170–182

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      151

       THE FOUR SCULPTED COLUMNS OF THE ST. MARK BASILICA’ CIBORIUM, VENICE: MARBLES, POLYCHROMY, PAST TREATMENTS

      IN: SIEGESMUND, S. & MIDDENDORF, B. (EDS.): MONUMENT FUTURE: DECAY AND CONSERVATION OF STONE.

       – PROCEEDINGS OF THE 14TH INTERNATIONAL CONGRESS ON THE DETERIORATION AND CONSERVATION OF STONE –

       VOLUME I AND VOLUME II. MITTELDEUTSCHER VERLAG 2020.

       Abstract

      The famous four marble columns of the ciborium are among the most important artifacts preserved in St. Mark’s Basilica, Venice. Carved with scenes of Christ and Mary’s lives by two masters in Constantinople in the first half of the 6th century BC, they were subsequently pillaged from an unknown church by the Venetians soon after the 1204 Crusader’s sack of the city. Reworked and gilded in Venice, they were re-installed after the 1222 earthquake in the ciborium covering the sarcophagus of the evangelist and the main altar. Thought to be made of oriental alabaster, they have been subject to many treatments throughout the centuries and the subject of extensive archaeometric study with identification of their materials, previous gildings and protective treatments. Micro-samples taken from each column were analysed by minero-petrographic (XRD, OM, SEM+EDS on thin and polished cross sections) and geochemical (SIRA, microFTIR and Raman spectroscopy) techniques. The results indicate that the columns consist of Dokymaean marble originating from three different quarries.The original gold leaf gilding was applied to a yellowish preparatory layer of lead-white mixed with other pigments subsequently covered by two later gildings, the most recent of which was laid on a red minium-ground. A protective/consolidation film of dammar, now discoloured into a brown coating, was identified together with other organic media such as siccative oils and proteinaceous substances and were probably applied in the XIX century and later.

       Introduction

      Saint Mark’s Basilica is the most important monument of Venice. Built as the private Ducal Chapel, it became the centre of religious life in 1806 when it became the town cathedral. Since its construction, the main altar of the Basilica holds the relics of the body of the evangelist, transported in 828 AD to Venice, by two sailors, Bono of Malamocco and Rustico of Torcello. The receipt of these relics prompted the initial building of the first Basilica, which was inaugurated two years later under the doge Giovanni Parteciaco. At the end of the 11th century, this was lavishly decorated with polychrome marbles but increasingly after the Fourth Crusade (1204), and has been restored many times up to the present day, with the continuous addition of altars and sculptures. At some point in the first half of the XIII century, likely after a strong earthquake in 1222, a ciborium was erected above the main altar (Wolters 2014: 145-6) with marble spoliated after the Latin’s 1204 sack of Constantinople. The ciborium has a square plan and an 152elevation of rectangular shape forming a four-sided baldachin that stands isolated in the middle of the presbiterium (Fig. 1). The vault is cross-shaped with external walls faced with marmor thessalicum (verde antico) (Lazzarini 1997: 324; Lazzarini 2007: 223–244); the covering roof holds six small stone statues, some of which are re-used from other monuments. The whole structure is supported by four marble Corinthian-style capitals made in Venice in the XIII century imitating Roman originals of the II century A. D. These are also

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