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addition of Grignard reagents to aldehydes cat...Scheme 16.2. Cu(I)‐catalyzed enantioselective addition of Grignard reagent t...Scheme 16.3. Arylation of ketones catalyzed by Ti/Binol (a) [21] and Mg/Bino...Scheme 16.4. Rh(I)‐catalyzed enantioselective addition of arylboroxines to k...Scheme 16.5. Rh‐catalyzed enantioselective arylation of keto esters (a) [31]...Scheme 16.6. Ni‐catalyzed enantioselective arylation of ketones with organob...Scheme 16.7. Cu(I)‐catalyzed enantioselective intramolecular addition of ary...Scheme 16.8. Catalytic enantio‐ and diastereoselective synthesis of adjacent...Scheme 16.9. Addition of allyl and allenyl organoboron reagents to ketones, ...Scheme 16.10. Enantioselective allylation of ketones containing a tri‐, a di...Scheme 16.11. Enantioselective allylboration of ketones catalyzed by 1,16‐di...Scheme 16.12. Zn(II)‐catalyzed enantioselective allenylation of ketones [44]...Scheme 16.13. Catalytic enantioselective propargylation of trifluoromethyl k...Scheme 16.14. Catalytic enantioselective propargylation of aryl ketones [47]...Scheme 16.15. Catalytic enantioselective arylation of ketones with organotit...Figure 16.2. Selection of bioactive and pharmaceutically active compounds co...Scheme 16.16. Cu(I)‐catalyzed enantioselective alkylation of silyl/aryl (a) ...Scheme 16.17. Rh(I)‐catalyzed enantioselective arylation of acyclic (a) [62]...Scheme 16.18. Rh(I)‐catalyzed enantioselective additions of arylboronic acid...Scheme 16.19. Rh(I)‐catalyzed enantioselective arylation of isatin‐derived N...Scheme 16.20. Pd(II)‐catalyzed enantioselective arylation of cyclic α‐ketimi...Scheme 16.21. Pd(II)‐catalyzed enantioselective arylation cyclic ketimines [...Scheme 16.22. Pd(II)‐catalyzed enantioselective arylation of trifluoromethyl...Scheme 16.23. Pd(II)‐catalyzed enantioselective arylation of isatin‐derived ...Scheme 16.24. Pd(II)‐catalyzed enantioselective arylation of cyclic seven‐me...Scheme 16.25. Ni(II)‐catalyzed enantioselective arylations (a) [94] and alke...Scheme 16.26. Co‐catalyzed enantioselective allylation of cyclic ketimines [...Scheme 16.27. Cu(I)‐catalyzed diastereoselective and enantioselective additi...Scheme 16.28. Catalytic Cu(I)‐catalyzed synthesis of C‐tertiary amine from u...Scheme 16.29. Alkenyl‐substituted N‐heteroaromatics as Michael acceptors in ...Scheme 16.30. Lewis acid enabled Cu(I)‐catalyzed conjugate additions to unac...Scheme 16.31. Cu(I)‐catalyzed enantioselective addition of Grignard reagents...Scheme 16.32. Cu(I)‐catalyzed enantioselective addition of Grignard reagents...Scheme 16.33. Cu(I)‐catalyzed enantioselective addition of Grignard reagents...Scheme 16.34. Cu(I)‐catalyzed enantioselective reactions with N‐heteroaromat...Scheme 16.35. Catalytic enantioselective conjugate additions of organozinc r...Scheme 16.36. Selection of successful chiral ligands developed for catalytic...Scheme 16.37. Cu(I)‐catalyzed conjugate additions of organozinc reagents to ...Scheme 16.38. Cu(I)‐catalyzed conjugate additions of organozinc reagents to ...Scheme 16.39. Selection of successful chiral ligands developed for catalytic...Scheme 16.40. Selection of successful chiral ligands developed for catalytic...Scheme 16.41. Cu(I)‐catalyzed conjugate additions of organozirconium reagent...Scheme 16.42. Cu(I)‐catalyzed conjugate additions of organozirconium reagent...Scheme 16.43. Rh(I)‐catalyzed conjugate additions of organoboron reagents to...Scheme 16.44. Rh(I)‐catalyzed conjugate additions of boronic acids to α,β‐un...Scheme 16.45. Rh(I)‐catalyzed conjugate addition of boronic acids to cyclic ...Scheme 16.46. Rh(I)‐catalyzed conjugate addition of organoboron reagent to a...Scheme 16.47. Copper(I)‐catalyzed conjugate addition of arylboron reagents t...Scheme 16.48. Rh(I)‐catalyzed conjugate addition of arylboronic acids to var...Scheme 16.49. Rh(I)‐catalyzed enantioselective synthesis of 3,3‐diaryl‐SPINO...Scheme 16.50. Selection of successful chiral ligands developed for catalytic...Scheme 16.51. Rh(I)‐catalyzed enantioselective synthesis of chiral indole (a...Scheme 16.52. Cu(I)‐carbene catalyzed conjugate additions to α,β‐unsaturated...Scheme 16.53. Rh(I)‐catalyzed enantioselective arylation of sulfolene (a) [2...Scheme 16.54. Rh(I)‐catalyzed enantioselective arylation of α,β‐unsaturated ...

      17 Chapter 17Scheme 17.1. Pd‐catalyzed asymmetric allylic alkylation of α‐nitro esters wi...Scheme 17.2. (a) Enantio‐ and diastereoselective deracemization of cis‐2‐oxa...Scheme 17.3. Oxidative and redox neutral Pd‐catalyzed allylic arylation with...Scheme 17.4. Pd‐catalyzed asymmetric allylic alkylation with vinylcyclopropa...Scheme 17.5. Hydroxyacrylate nucleophiles in the Pd‐catalyzed asymmetric all...Scheme 17.6. Pd‐catalyzed DYKAT of benzylic diarylmethyl carbonates.Scheme 17.7. Asymmetric allylic alkylation with Mortia–Baylis–Hillman adduct...Scheme 17.8. Pd‐catalyzed asymmetric allylic fluoroalkylation of cyclic ally...Scheme 17.9. Dearomative C₂ selective allylic alkylation of pyrrole nucleoph...Scheme 17.10. Pd‐catalyzed asymmetric allylic alkylation of in situ generate...Scheme 17.11. Allylic alkylation of enols with allyl alcohol via CO₂ activat...Scheme 17.12. Cu/Pd dual catalysis for the asymmetric allylic alkylation of ...Scheme 17.13. Pd/Cu dual catalysis for enantio‐ and diastereodivergent allyl...Scheme 17.14. Merger of photoredox catalysis and Pd‐catalyzed enantioselecti...Figure 17.1. Enantioenriched motifs accessed by Stoltz via decarboxylative a...Figure 17.2. Substrate classes prepared via Pd‐catalyzed decarboxylative all...Scheme 17.15. Asymmetric decarboxylative propargylation of α‐aryl indanones....Scheme 17.16. Michael acceptor interrupted Pd‐catalyzed allylic alkylation....Scheme 17.17. Decarboxylative allylic alkylation of benzoxazolinone‐derived ...Scheme 17.18. (a) Acyclic stereocontrol in amides.(b) Acyclic stereocont...Scheme 17.19. Ni‐catalyzed asymmetric allylic alkylation of diarylmethanes a...Scheme 17.20. Ni‐catalyzed allylic alkylation of cyclic β‐ketoesters with un...Scheme 17.21. Ni‐catalyzed allylic alkylation of α‐acyl lactones with unacti...Scheme 17.22. Ni‐catalyzed allylic alkylation of cyclic β‐ketoesters with N‐...Scheme 17.23. Ni‐catalyzed allylic alkylation of acyclic acyl imidazoles wit...Scheme 17.24. Ni‐catalyzed Suzuki‐type cross‐coupling of pro‐quinolinium ele...Scheme 17.25. Mo‐catalyzed allylic alkylation of acyclic α‐cyanoesters.Scheme 17.26. (a) Cyclopentadienyl ruthenium complex catalyzed allylic alkyl...Scheme 17.27. (a) Rh‐catalyzed DYKAT of cyclic allylic bromides and chloride...Scheme 17.28. (a) Enantioselective Rh‐catalyzed allylic alkylation of acycli...Scheme 17.29. (a) Rh‐catalyzed allylic alkylation of 1,3‐diketones with ally...Scheme 17.30. (a) Ir‐catalyzed allylic alkylation of 3‐fluorosubstituted ele...Scheme 17.31. (a) First report of an MAC nucleophile in the Ir‐catalyzed all...Scheme 17.32. Counterion‐controlled diastereoselective Ir‐catalyzed allylic ...Scheme 17.33. (a) Diastereo‐ and enantioselective allylic alkylation of 5H‐o...Scheme 17.34. (a) Ir‐catalyzed allylic alkylation of cyclic β‐ketoesters. (b...Scheme 17.35. Ir‐catalyzed regio‐, diastereo‐, and enantioselective allylic ...Scheme 17.36. (a) Tandem Ir‐catalyzed allylic alkylation/Cope rearrangement....Scheme 17.37. Ir‐catalyzed enantioselective allylic alkylation with crotyl c...Scheme 17.38. Stereodivergent Ir‐catalyzed catalyzed allylic alkylation via ...Scheme 17.39. Ir‐catalyzed allylic alkylation of trimethylsiloxy furan.Scheme 17.40. Diastereo‐ and enantioselective allylic alkylation of non‐stab...Scheme 17.41. Dual‐catalytic stereodivergence in the Ir‐catalyzed allylic al...Scheme 17.42. Desymmetrizing CADA of bisphenol derivatives.Scheme 17.43. Allyl–olefin coupling via Ir‐catalyzed allylic substitution....Scheme 17.44. Ir‐catalyzed allylic alkylation with functionalized organozinc...Scheme 17.45. Formal umpolung allylation of N‐fluorenyl imines.Scheme 17.46. Cu‐catalyzed allylic alkylation of organolithium reagents.Scheme 17.47. (a) Cu‐catalyzed asymmetric allylic alkylation of allylic chlo...Scheme 17.48. (a) Enantioselective allylic arylation of allylic bromides to ...Scheme 17.49. (a) Enantioselective allylic alkylation of alkynylaluminum for...Scheme 17.50. Cu‐catalyzed enantioselective allylic alkylation with organobo...Scheme 17.51. Cu‐catalyzed asymmetric allylic allenylation with bench‐stable...Scheme 17.52. Cu‐catalyzed allylic alkylation of alkyl boranes with Z‐allyli...Scheme 17.53. Dynamic kinetic asymmetric allylic alkylation of alkylzirconiu...Scheme 17.54. Cu‐catalyzed allylic alkylation with terminal alkyne nucleophi...Scheme 17.55. Cu‐catalyzed allylic alkylation of formidyl cuprates.Scheme 17.56. Cu‐catalyzed enantioselective allylic alkylation of γ‐butyrola...Scheme 17.57. First example of a highly enantio‐ and regioselective Co‐catal...Scheme 17.58. Enantio‐ and regioselective Co‐catalyzed allylic alkylation of...Scheme 17.59. Organophotoredox approach to Co‐catalyzed enantioselective all...

      18 Chapter 18Scheme 18.1. Carbometallation of alkynes and alkenes.Scheme 18.2. Asymmetric carbometallation of alkenes.Scheme 18.3. ZACA reactions of allyl alcohols.Scheme 18.4. ZACA reactions of tert‐butyldimethylsilyl‐protected

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