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order to solve these problems, some groups have developed pulse X‐ray‐based instruments for scintillation decay measurement. Pioneering work was done by the Lawrence Berkeley Laboratory (USA) with the cooperation of Hamamatsu Photonics (Japan) [91]. The key technology is a stable pulse X‐ray source which can be used at laboratory level, and if such a source is developed, we can use the same data processing system with PL decay and DCM. In this pulse X‐ray tube, the origin of the excitation is a laser diode or LED, and emits visible photons with 10–106 Hz frequency, depending on the time range of measurement. Emitted visible photons hit a multi‐alkali photocathode of the X‐ray tube, and are converted into electrons. These electrons are accelerated by high voltage bias, and are lead to a tungsten target by a strong electric field. Then, bremsstrahlung X‐rays are generated and irradiated to the sample through a Be window. In this way, we can make a pulse X‐ray by the timing of laser diode or LED and use it as a start signal.

      We now introduce some applications of this pulsed X‐ray tube for scintillation decay measurement. The timing resolution of an X‐ray tube is several tens ps, which is determined by the traveling time of accelerated electrons, and it is enough to measure the rise time of most scintillators [92]. Following these pioneering works, a pulse X‐ray equipped streak camera system was developed, and enabled us to observe the wavelength resolved scintillation decay curve [93]. In this system, the detection part consists of a spectrometer chamber, streak camera, and two‐dimensional CCD, and a two‐dimensional image of wavelength vs. time can be observed. By the streak system, one of the problems of DCM, non‐wavelength resolution, can be solved. Up until the development of the streak camera system, every study used a pulse laser diode as the root of the excitation source, and it was enough to measure fast‐timing events. However, it is not sufficient to measure slow events, especially in the ms time range. One of the solutions for ms measurement is to replace the excitation source to common LED, which has higher power than the pulse‐type laser diode but slower speed. The pulse LED type system was developed in 2014 [94]. This system enabled us to measure slow (ms) scintillation decay as well as the X‐ray induced afterglow. Because the signal intensity per unit time is very low in slower scintillation, the system does not offer the function of wavelength resolution, and the detection part is one PMT. When we compare with typical measurements by DCM, the measurement time dramatically decreases to a few minutes for one sample. At present, no significant difference of excitation energy between 511 keV (DCM) and several tens keV (pulse X‐ray tube) has been found.

      In other ionizing radiations such as α‐ray, measurement is generally difficult. One easy but rough way is to use an oscilloscope for direct observation of the signal output from a detector, consisting of scintillator and photodetector by a self‐trigger mode. Although it may contain noise (e.g., thermal noise of photodetector), we can roughly observe scintillation decay time. Previously, most papers observed decay curves by such an oscilloscope measurement, but recently, a digitizer has been used to accumulate many decay curves. In such a case, we can accumulate a large amount of decay curves, and select correct decay curves by setting correct selection conditions of events. An accurate but technically difficult way is to use DCM by one scintillator sample and two photodetectors. If we take the case of α‐ray irradiation as an example, let us assume one cylindrical scintillator optically coupled with two PMTs by edge surfaces, and α‐ray is irradiated to the side of the scintillator. When the α‐ray is absorbed by the center part of the scintillator, half of the scintillation photons are transported to one PMT and the other remaining half to another PMT. We can use one of the two output signals as a start signal, and if we can reduce the number of photons in another side to a single photon, we can use it as a stop signal. In this way, we can measure scintillation decay under particle excitation.

      The pulse height spectrum is one of the most important properties of scintillation detectors, because most of measurements in other scientific fields use integration‐type detectors, and pulse height (photon counting) type measurements is one of the original techniques in radiation and high energy physics. The detailed explanation is given in Chapter 12.

      In characterizations of OSL and RPL, we generally use common systems of PL spectrum. In OSL, after the irradiation of ionizing radiation, we put the sample in a PL machine and stimulate the sample under the adequate stimulation wavelength. In some spectrofluorometers, the automatic measurement function of PL excitation spectrum is installed, and by this function, we can easily investigate the stimulation spectrum. Unlike the PL excitation spectrum, which generally shows a clear excitation band due to electron transitions of dopant, OSL stimulation spectrum generally shows a broad unclear feature. For OSL and TSL measurements, an automation type instrument (Risø TL/OSL DA‐20 reader) is widely used ([95]). Generally, this system equips β‐ray (90Sr) as an irradiation source, LED as a stimulation source for OSL having typically a 470 nm emission wavelength, and a heater for TSL measurement. One of the disadvantages of this automated system is a lack of wavelength resolution, which equals to non‐determination capability on the emission origin, and some ideas are proposed to add a function of wavelength resolution [96].

      In order to investigate OSL and RPL, some important aspects should be noted in actual experiments. Typically, the stimulation wavelength of OSL is longer than the emission wavelength, and resembles the situation of upconversion. In order to distinguish them, continuous stimulation is a simple way. If the phenomenon is OSL, the emission intensity decreases under the continuous stimulation, while in the case of upconversion, the intensity is constant. In addition, the stimulation wavelength of OSL is not necessarily longer than the emission wavelength, because we cannot deny the existence of a deep trap. In such a case, distinction of OSL and RPL becomes difficult. The continuous stimulation (excitation) is also a useful technique in this situation, and if the phenomenon is OSL, the emission intensity decreases with time, while that of RPL is constant against time. But in the special case where the trap depth and excitation band overlap, clear distinction is difficult. Other experimental aspects of OSL and RPL are introduced in Chapters 8 and 9, respectively.

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