Concise Handbook of Fluorocarbon Gases - Sina Ebnesajjad

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chlorine) known as the third generation of fluorocarbons.

      Hydrobromofluorocarbons contain Hydrogen, Bromine, Fluorine, and Carbon atoms. Perfluorocarbons contain Fluorine, Carbon, and Bromine atoms, and some contain Chlorine and/or Hydrogen atoms.

      Table 2.1 Examples of various acyclic alkane fluorocarbons.

Compound Chemical formula Form
Hexane CH3-CH3 Alkane
Perfluorohexane CF3-CF3 Perfluorinated
2-bromo-2-chloro-1,1,1- trifluoroethane (Halothane) CF3-CHBrCl Fluorobromochlorinated
1,2-dichloro-1,1,2-trifluoroethane CClF2-CHClF Hydrochlorofluorocarbon
1,1,2-Trifluoroethane CHF2-CH2F Hydrofluorocarbon

      To avoid repeating the rather long chemical names of fluorocarbons a system has been devised to use codes for each of them. Oak Ridge National Laboratory [6] has provided the designations of fluorocarbon codes (Section 2.2.1).

      Fluorocarbon compounds are designated by a combination of letters and numbers (e.g., CFC-11, HCFC-142b). In the latter example, the lower-case b refers to an isomer. It has no relationship to the chemical formula (C2H3F2Cl), rather it designates a particular structural arrangement of the atoms in the molecule. For example, HCFC-142b identifies the isomer in which all three hydrogen atoms are attached to the same carbon atom, and the structural formula is written as CH3CF2Cl. By contrast, HCFC-142 (without the b) refers to an arrangement in which one carbon atom is attached to two hydrogen atoms and one chlorine atom, while the other carbon atom is attached to the third hydrogen atom and two fluorine atoms (CH2ClCHF2).

      To find the number, given the chemical formula: consider the number as consisting of 3 digits: a, b, and c. For 2-digit numbers (e.g., CFC-11) one digit is zero (e.g., CFC-011).

       a is the number of carbon atoms minus 1;

       b is the number of hydrogen atoms plus 1;

       c is the number of fluorine atoms.
For CFCl3: a = the number of carbon atoms (1) minus 1 = 0
b = the number of hydrogen atoms (0) plus 1 = 1
c = the number of fluorine atom = 1

      and the compound is CFC-011, or CFC-11.

      Similarly:

      CCl2F2 is CFC-012

      C2Cl3F3 is CFC-113

      To find the chemical formula, given the number: first add 90 to the abc number, to obtain a 3-digit definite number (def), where:

       d is the number of carbon atoms;

       e is the number of hydrogen atoms;

       f is the number of fluorine atoms; and

       2d + 2 - e - f = the number of chlorine atoms.

      For CFC-11: 90 + 11 = 101, so the number of carbon atoms is 1, the number of hydrogen atoms is zero, the number of fluorine atoms is 1, and the number of chlorine atoms is (2 + 2 - 0 - 1 = 3). So the chemical formula for CFC-11 is CFCl3. That is, it has 1 carbon atom, no hydrogen, 1 fluorine atom, and 3 chlorine atoms.

CFC-12: 12 + 90 = 102; 4-2 = 2 Cl; the chemical formula is: CCl2F2 CFC-113: 113 + 90 = 203; 6-3 = 3 Cl; the chemical formula is: C2Cl3F3 HCFC-142b: 142 + 90 = 232; 6-5 = 1 Cl; the chemical formula is: C2H3F2Cl

      Halons are fluorocarbons with at least one bromine atom.

      Halon (no hydrogen number) nomenclature is relatively simple; each halon has an abcd number, where:

       a = the number of carbon atoms;

       b = the number of fluorine atoms;

       c = the number of chlorine atoms, and

       d = the number of bromine atoms.

      C2F4Br2 is Halon 2402. And, an example going the other way Halon 1211 is CF2ClBr. It is not possible to speak about fluorocarbons without bringing up the issue of the effect of these compounds on the Earth’s Ozone Layer and the Montreal Protocol (described later in this section) that has banned most or all of those fluorocarbons. Examples of the three main commercial classes, based on their interaction with ozone, of fluorocarbons are summarized in Table 2.2. CFC’s have been completely phased out and the others, except for HFOs, are in various stages of being phased out.

      Hydrofluorocarbons and, to a very limited extent, perfluorocarbons (PFCs), serve as alternatives to ozone depleting substances phased out under the Montreal Protocol. Tables 2.3 and 2.4 summarize HCFC, HFCs and PFCs fluorocarbons. Applications of HFCs are presented in Table 2.5.

      The usage of olefinic fluorocarbons required an extension of the designation system by ASHRAE (American Society of Heating, Refrigerating and Air-Conditioning Engineers). The following descriptions have been adopted from an ASHRAE publication [10].

      Olefin: an organic (carbon containing) compound characterized by the presence of one or more double bonds between carbon atoms in the molecule. Such a compound can also be described as being unsaturated.

      Unsaturated: as used in this standard, an organic (carbon containing) compound in which one or more carbon atom is joined to other carbon atoms by a carbon-carbon double bond. Such a compound can also be described as an olefin.

      The identifying numbers assigned to the hydrocarbons and halocarbons of the methane, ethane, ethene, propane, propene, and cyclobutane series are such that the chemical composition of the compounds can be explicitly determined from the refrigerant numbers, and vice versa, without ambiguity. The molecular structure can be similarly determined for the methane, ethane, ethene, and most of the propane and propene series from only the identification number.

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