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The History of Chemistry. Thomas Thomson
Читать онлайн.Название The History of Chemistry
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isbn 4064066382971
Автор произведения Thomas Thomson
Жанр Математика
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2. Six pounds of iron wire were put into a large glass body, and twelve pounds of muriatic acid poured upon it. Six days elapsed (during which it stood in a gentle heat) before the acid was saturated with the iron. The solution was then decanted off, and filtered, and six pounds of new muriatic acid poured on the undissolved iron. This acid, after standing a sufficient time, was decanted off, and filtered. Both liquids were put into a large retort, and distilled by a sand-heat. Towards the end, when the drops from the retort became yellow, the receiver was changed, and the fire increased to the highest degree, in which the retort was kept between four and six hours. When all was cold, the receiver was taken off, and a quantity of flowers was found in the neck of the retort, variously coloured, like the rainbow. The yellow liquor in the receiver weighed ten ounces and a half; the flowers (chloride of iron), two ounces and three drams. The liquid and flowers were put into a clean bottle.
3. Half a pound of sal enixum (sulphate of potash) and a pound and a half of nitric acid were put into a retort. When the salt had dissolved in the acid, ten ounces of mercury (previously distilled through quicklime and salt of tartar) were added. The whole being distilled to dryness, a fine yellow mass (pernitrate of mercury) remained in the bottom of the retort. The liquor was returned, with half a pound of fresh nitric acid, and the distillation repeated. The distillation was repeated a third time, urging this last cohobation with the highest degree of fire. When all was cold, a various-coloured mass was found in the bottom of the retort: this mass was doubtless a mixture of sulphate of potash, and pernitrate of mercury, with some oxide of mercury.
4. Four ounces of fine silver were dissolved in a pound of aqua fortis; to the solution was added, of the bisulphuret of copper four ounces; of the mixture of sulphate of potash, pernitrate of mercury, and oxide of mercury one ounce and a half, and of the solution of perchloride of iron two ounces and a half. When these had stood in a retort twenty-four hours, the liquor was decanted off, and four ounces of nitric acid were poured upon the little matter that was not dissolved. Next morning a total dissolution was obtained. The whole of this dissolution was put into a retort and distilled almost to dryness. The liquid was poured back, and the distillation repeated three times; the last time the retort being urged by a very strong fire till no fumes appeared, and not a drop fell.
5. The matter left in the bottom of the retort was now put into a crucible, all the corrosive fumes were gently evaporated, and the residue melted down with a fluxing powder.
This process was expected to yield five ounces of pure gold; but on examination the silver was the same (except the loss of half a pennyweight) as when dissolved in the aqua fortis: there were indeed some grains among the scoria, which appeared like gold, and would not dissolve in aqua fortis. No doubt they consisted of peroxide of iron, or, perhaps, persulphuret of iron.15
Mr. Wilson’s alchymistical friend, not satisfied with this first failure, insisted upon a repetition of the process, with some alteration in the method and the addition of a certain quantity of gold. The whole was accordingly gone through again; but it is unnecessary to say that no gold was obtained, or at least, the two drams of gold employed had increased in weight by only two scruples and thirteen grains; this addition was doubtless owing to a little silver from which it had not been freed.16
I shall now give a process for making the philosopher’s stone, which was considered by Mangetus as of great value, and on that account was given by him in the preface to his Bibliotheca Chemica.
1. Prepare a quantity of spirit of wine, so free from water that it is wholly combustible, and so volatile that when a drop of it is let fall it evaporates before it reaches the ground;—this constitutes the first menstruum.
2. Take pure mercury, revived in the usual manner from cinnabar, put it into a glass vessel with common salt and distilled vinegar; agitate violently, and when the vinegar acquires a black colour pour it off and add new vinegar; agitate again, and continue these repeated agitations and additions till the vinegar ceases to acquire a black colour from the mercury: the mercury is now quite pure and very brilliant.
3. Take of this mercury four parts; of sublimed mercury17 (mercurii meteoresati), prepared with your own hands, eight parts; triturate them together in a wooden mortar with a wooden pestle, till all the grains of running mercury disappear. This process is tedious and rather difficult.
4. The mixture thus prepared is to be put into an aludel, or a sand-bath, and exposed to a subliming heat, which is to be gradually raised till the whole sublimes. Collect the sublimed matter, put it again into the aludel, and sublime a second time; this process must be repeated five times. Thus a very sweet and crystallized sublimate is obtained: it constitutes the salt of wise men (sal sapientum), and possesses wonderful properties.18
5. Grind it in a wooden mortar, and reduce it to powder; put it into a glass retort, and pour upon it the spirit of wine (No. 1) till it stands about three finger-breadths above the powder; seal the retort hermetically, and expose it to a very gentle heat for seventy-four hours, shaking it several times a-day; then distil with a gentle heat and the spirit of wine will pass over, together with spirit of mercury. Keep this liquid in a well-stopped bottle, lest it should evaporate. More spirit of wine is to be poured upon the residual salt, and after digestion it must be distilled off as before; and this process must be repeated till the whole salt is dissolved, and distilled over with the spirit of wine. You have now performed a great work. The mercury is now rendered in some measure volatile, and it will gradually become fit to receive the tincture of gold and silver. Now return thanks to God, who has hitherto crowned your wonderful work with success; nor is this great work involved in Cimmerian darkness, but clearer than the sun; though preceding writers have imposed upon us with parables, hieroglyphics, fables, and enigmas.
6. Take this mercurial spirit, which contains our magical steel in its belly, put it into a glass retort, to which a receiver must be well and carefully luted: draw off the spirit by a very gentle heat, there will remain in the bottom of the retort the quintessence or soul of mercury; this is to be sublimed by applying a stronger heat to the retort that it may become volatile, as all the philosophers express themselves—Si fixum solvas faciesque volare solutum,
Et volucrum figas faciet te vivere tutum.
This is our luna, our fountain, in which the king and queen may bathe. Preserve this precious quintessence of mercury, which is very volatile, in a well-shut vessel for further use.
8. Let us now proceed to the operation of common gold, which we shall communicate clearly and distinctly, without digression or obscurity; that from vulgar gold we may obtain our philosophical gold, just as from common mercury we obtained, by the preceding processes, philosophical mercury.
In the name of God, then, take common gold, purified in the usual way by antimony, convert it into small grains, which must be washed with salt and vinegar, till it be quite pure. Take one part of this gold, and pour on it three parts of the quintessence of mercury; as philosophers reckon from seven to ten, so we also reckon our number as philosophical, and we begin with three and one; let them be married together like husband and wife, to produce children of their own kind, and you will see the common gold sink and plainly dissolve. Now the marriage is consummated; now two things are converted into one: thus the philosophical sulphur is at hand, as the philosophers say, the sulphur being dissolved the stone is at hand. Take then, in the name of God, our philosophical vessel, in which the king and queen embrace each other as in a bedchamber, and leave it till the water is converted into earth, then peace is concluded between the water and fire, then the elements have no longer any thing contrary to each other; because, when the elements are converted into earth they no longer oppose each other; for in earth all elements are at rest. For the philosophers say, “When you shall have seen the water coagulate itself, think that your knowledge is true, and that your operations are truly philosophical.” The gold is now no longer common, but ours is philosophical, on account of our processes: at first exceedingly fixed; then exceedingly volatile, and finally exceedingly fixed; and the whole science depends upon the change of the elements. The gold at first was a metal, now it is a sulphur, capable of converting all metals into its own sulphur. Now our tincture