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processes. Bio‐products include a wide variety of products from those with low value and high volume, such as glycerin and lactic acid, to those with high value and low volume, such as those used in food or pharmaceuticals industries (Langeveld et al., 2010). Biofuels include gas, liquid, or solid fuel types produced directly or indirectly from biomass. The bio‐based systems in this book chapter refer to those which are used to produce agricultural crop‐based biofuels.

      3.1.1. Bio‐Based Systems for Achieving the Sustainable Development Goals

Schematic illustration of carbon cycle of biofuels.

      3.1.2. Interconnection of Water and Energy in Bio‐Based Systems

      Water and energy are two necessary resources for human life. Energy production from bio‐based systems can reduce the environmental impacts and increase the energy security of the nations by reducing the reliance on fossil fuels. Water being a scarce source is important in biobased systems. Thus, bio‐based systems can contribute help achieve the global climate change mitigation goals, but this needs valuable resources such as water and energy in the process. Some of the other key concerns associated with the development of bio‐based systems include food security because of the use of food crops for energy supply, risks of increased emissions during biomass production and processing, and reduction in biodiversity due to land use change by expansion of bioenergy crops. External factors such as lack of economic competitiveness of biofuels with petroleum‐based fuels is also restricting the expansion of bio‐based systems for energy purposes. Development of bio‐based systems that advance the SDGs requires policies and measures to ensure sustainability of the systems (IRENA, 2019), including a rational use of energy and water throughout the entire cycle.

      3.1.3. Overview of the Chapter

      The goal of this chapter is to exhibit the interactions of water and energy in the development of bio‐based systems as a mean for achieving the SDGs. Accordingly, energy use and supply in bio‐based systems are explained, and water supply for bio‐based energy production as well as the role of bio‐based energy in water supply are discussed. Then, the water‐energy nexus in bio‐based systems is presented, and finally the tools and metrics for quantifying the sustainability of water‐energy nexus are explained.

      3.2.1. Water Availability

      More than two thirds of the earth’s surface is covered with water (USGS, 2016). However, ~97.5% of that is saltwater which cannot be used for industrial, agricultural, or residential purposes. Of the remaining freshwater, ~1.75% is frozen in glaciers, and the rest is available as ground water (~0.68%) and freshwater in lakes and rivers (0.07%) (USGS, 2016). Freshwater is used for residential purposes (11%), industries (19%), and agriculture (70%) (FAO, 2016). Water is essential in all sectors, and bio‐based systems utilize large quantities of water, increasing the pressure on this already scarce resource. Water in bio‐based systems is not the most expensive input; however, unlike other resources, it has no substitutes. Water is required at different stages in bio‐based systems, from irrigation during biomass production up to recovery of the final products after biomass processing. However, water consumed during biomass production and processing have different intensities of water use. Water used for irrigation during biomass production is consumed in the process, which means no wastewater is generated. However, some of the water used during the processing may be reused by wastewater treatment and purification processes. Steam used in the process can also be reused after being condensed to water.

      3.2.2. Water Use in Biomass Production

      Bioethanol is the main biofuel produced worldwide. The two largest crops for ethanol production are corn in the US and sugarcane in Brazil. Most of the US corn is produced under rainfed conditions; however, in areas where it is irrigated, water is mainly supplied from groundwater sources, such as the Ogallala Aquifer which supplies irrigation water for ~45 million ha of land in eight states of the US (Maupin and Barber, 2005). Sugarcane is a perennial crop, with high concentration of sugar juices, which is mostly produced under rainfed conditions (Moreira, 2007). Irrigation is becoming necessary as sugarcane production is expanding to arid areas (Goldemberg et al., 2008). Irrigation needed for most of the crops grown for food, except corn, is higher than that for dedicated energy crops, such as switchgrass, miscanthus, willow, poplar, and eucalyptus (Fraiture and Berndes, 2009). Corn production in the US needs low quantities of water, because it is grown in areas with enough rainfall (Le et al., 2011; VanLoocke et al., 2012; Wu and Liu, 2012). Other types of biomass used for energy production, such as sewage sludge and

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