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and exposure transducer were placed.

Schematic illustration of the placement of the test device.

      It should be noted that the injected fluid in this experiment is CO2 supercritical, which has been injected under 1300 psi pressure and a temperature of 46 °C at a rate of 1 (ml/min) into the sample saturated with distilled water.

Schematic illustration of the placement of sample with transducer and the top cap. Photos depict (a) the core flooding system, (b) the holder connected to the core and transducers.

      2.3.1 Laboratory Data Collection

Schematic illustration of compressional and shear wave velocity vs different effective pressure for super critically saturated core sample. Schematic illustration of P-wave velocity (experimental and estimated) at different effective pressures.

      In Figure 2.6, the compressional wave velocity obtained from the laboratory experiment and the Gassmann equation is depicted versus effective pressure. It can be noticed that at all effective pressures the estimated velocities have higher values than experimental ones. The difference gradually enlarges as the effective pressure is increased. The rate of velocity increment is faster for estimated velocity than the experimental counterpart. This is because in Gassmann theory environment (the core) is considered a homogeneous and isotropic elastic environment. This theory is often true for Monomineralic rocks such as pure quartz sandstone or clean limestone. But since the sample used in this study developed naturally, possible impurities exist such as clay or fine cracks; so wave scattering is not considered in the Gassmann equations. It is also effective on bulk modulus and often in this hypothesis, it is assumed to be average. Another issue to the assumptions of this model is the fluid replacement instead of several fluids, regardless of their distribution in the environment and is often considered to be the average of the density of the fluids. This is effective on the accuracy of the model especially while the saturation is not uniform (Patchy saturation). Also with the pressure increasing, joints and cracks closed more and reduced permeability. Therefore, fluid flow and the opportunity to achieve balance are much reduced and the operating result is that Gassmann theory pushes farther than expected.

      Shear wave velocity of the rock sample was determined at the different pressure from the estimated compressional wave velocity, using Greenberg-Castagna formulas.