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structures
4. (b) Schematic representation of the donor–acceptor–donor molecules
5, which assembled due to π–π stacking interactions of their outer electron‐rich chromophores. Source: Lee et al. [18], © 2011 John Wiley and Sons.Figure 5.8 Schematic representation of representative core‐unsubstituted PBI dyes (
6–
10).Figure 5.9 Schematic representation of representative bay‐substituted PBI dyes (
11 and
12).Figure 5.10 (a) Representation of the color tunability of the emission of
6a in solution, the red emission from a spin‐coated film of
6a is shown on the very right. (b) POM image of the LC phase of
6a. Source: Chen et al. [25]. Figure reproduced with kind permission; © 2007 Wiley‐VCH.Figure 5.11 (a) Schematic representation of the proposed columnar stacking mode of PBI molecules. (b) Plot of the standard Gibbs free energy (Δ
G0) for an isodesmic aggregation process vs. the solvent polarity parameter [
ET(30)] for
6a (●x025CF;) and
6c (▲x025B2;). Source: Chen et al. [26], © 2012 The Royal Chemical Society.Figure 5.12 Schematic representation of the equilibrium between
6d and its aggregates in solution. At low a concentration and/or a high temperature, dimers of
M‐type helicity were preferred; whereas, at high concentrations and/or low temperatures, extended polymeric stacks of
P‐configuration were formed. Source: Dehm et al. [31], © 2007 American Chemical Society.Figure 5.13 Schematic representation of the solvent‐dependent self‐assembly/disassembly behavior observed for a binary mixture of
7 and an OPV derivative. Source: van Herrikhuyzen et al. [32], © 2004 American Chemical Society.Figure 5.14 Scanning electron microscopy images of the nanobelts and nanoparticles obtained from the self‐assembly of
9a and
10b, respectively. Source: Balakrishnan et al. [34]. Figure reproduced with kind permission; © 2006 American Chemical Society.Figure 5.15 Schematic representation of the two different stacking modes: Longitudinally displaced J‐type stacking of
11a (a) and rotationally displaced cofacial stacking of
11c (b). Source: Chen et al. [37]. © 2007 John Wiley and Sons.Figure 5.16 Schematic representation of amphiphilic squaramide dyes which gave supramolecular polymers due to dipolar π–π stacking interactions. Source: Bujosa et al. [49], © 2020 The Royal Chemical Society.Figure 5.17 Schematic representation of the boron‐centered triangulene
13 that self‐assembled into a columnar LC phase. Source: Kushida et al. [55]. © 2015 John Wiley and Sons.Figure 5.18 (a) Schematic representation of the different packing modes of bowl‐shaped molecules (from the non‐columnar type‐C assemblies only one representative example is shown). (b) Schematic representation of the P‐centered triangulenes
14. Source: Yamamura et al. [56], © 2016 American Chemical Society.Figure 5.19 Schematic representation of the competition between the homo‐ and hetero‐type stacking of donor–acceptor‐type molecules driven by π–π and charge–transfer stacking forces, respectively. Source: Modified from Han et al. [59].Figure 5.20 Schematic representation of the synthesis of an amphiphilic D–A‐type foldamer and its self‐assembly into a 1D nanostack. Source: Jalani et al. [64], © 2013 Royal Society of Chemistry.Figure 5.21 Schematic representation of the amphiphilic donor–acceptor molecule
17 that could assemble into nanosheets or vesicles depending on its conformation. Source: Jalani et al. [65]. Licenced under CC BY 3.0.Figure 5.22 Schematic representation of the various types of molecular tweezers/guest recognition motifs. (a) DAD‐ and ADA‐type assemblies, (b) DADA‐ and ADADA‐type assemblies and (c) self‐complementary and head‐to‐tail dimerization. Source: Han et al. [59], © 2018 The Royal Chemical Society.Figure 5.23 Schematic representation of the metal‐induced activation (a) and deactivation (b) of molecular tweezers according to Petitjean et al. [71].Figure 5.24 Schematic representation of the formation of a π‐electron ion pair via ion metathesis. Source: Haketa and Maeda [72], © 2017 Royal Society of Chemistry.Figure 5.25 Schematic representation of the three different self‐assembly modes of π‐electron ion pairs: charge‐by‐charge (a), charge segregated (b), and intermediate stacking (c). Source: Dong and Maeda [74].Figure 5.26 Schematic representation of the formation of a
π‐electron anion via the supramolecular complexation of a (halide) ion by a planar anion receptor. (a) cartoon representation and (b) at the example of
18. Source: Dong and Maeda [74], © 2013 Royal Society of Chemistry.Figure 5.27 Schematic representation of the formation of π‐electron anions by deprotonation of OH‐groups.Figure 5.28 Schematic representation of the π‐electron ion pairs, based on the cycloheptatrienyl (Ch
+) cation and cyclopentadienyl anions (
21−). The representations show the packing mode of [Ch][
21b] in the solid state (three different views are depicted). Source: Bando et al. [85], © 2016 John Wiley and Sons.Figure 5.29 (a) Schematic representation of the TATA
+ cation
22 and of the receptor–anion complex [
23⋅⋅⋅Cl]
−. (b) POM images, XRD patterns (at 101 °C) and proposed packing modes (from left to right) of the ion pairs [
22][
23⋅⋅⋅Cl] (a). Source: Haketa et al. [86]. Figure reproduced with kind permission; © 2010 Wiley‐VCHFigure 5.30 Schematic representation of the square‐planar Pt(II) complexes
24. The XRD pattern and the proposed packing mode for the ion‐pairing assembly of
24b and [
23⋅⋅⋅Cl]
− is also shown. Source: Sekiya et al. [89], © 2014 Royal Society of Chemistry.Figure 5.31 Schematic representation of the molecular tweezers
25 and their reversible self‐assembly of
25a into a linear supramolecular polymer. Source: Kim et al. [90], © 2012 American Chemical Society.Figure 5.32 Schematic representation of the pH‐switchable molecular tweezers
26 that were used for the assembly of a packed liposome bilayer with 1,2‐dioctadecanoyl‐
sn‐glycero‐3‐phosphocholine (DSPC) and
N‐(carbonyl‐methoxypolyethyleneglycol‐2000)‐1,2‐distearoyl‐
sn‐glycero‐3‐phosphoethanolamine (DSPE‐PEG
2000). The packed liposome bilayer collapsed upon acidification. Source: Viricel et al. [94].© 2015 John Wiley and Sons.Figure 5.33 Schematic representation of the molecular tweezers
27 containing two positively‐charged organoplatinum(II) pincers. Source: Tanaka et al. [95], © 2013 John Wiley and Sons.Figure 5.34 Schematic representation of the reversible supramolecular polymerization of
28. Source: Tian et al. [96], © 2014 John Wiley and Sons.Figure 5.35 Schematic representation of the complementary homoditopic monomers
29 and
30 and their supramolecular polymerization in a DADA‐type fashion. The evolution of the specific viscosity as a function of the monomer concentration is also shown. Source: Tian et al. [97], © 2016 American Chemical Society.Figure 5.36 Schematic representation of the porphyrin‐based molecular tweezers
31 and of the self‐complementary dimerization of
31a. Source: Haino et al. [68], © 2006 American Chemical Society.Figure 5.37 Schematic representation of the supramolecular polymerization of
32. Source: Modified from Haino et al. [99].Figure 5.38 Schematic representation of the heteroditopic monomers
33 and of the supramolecular polymerization of
33a. The specific viscosity of
33a in CHCl
3 (white circles) and toluene (black circles) at 293 K is also depicted. Source: Haino et al. [100], © 2012 John Wiley and Sons.Figure 5.39 Schematic representation of the bis‐pyridine derivative
34 that was used for the formation of a supramolecular polymer network in combination with
33b. A picture of the free‐standing polymer film of this material is also shown. Source: Hager et al. [102]. Figure reproduced with kind permission; © 2015 Wiley‐VCH.Figure 5.40 Schematic representation of the calix[4]pyrroles
35 that adopted a 1,3‐alternate conformation, which could accommodate two guest molecules via CT interactions. The conformation of
35 could be switched reversibly by adding chloride anions. Source: Nielsen et al. [107], © 2004 American Chemical Society.Figure 5.41 Schematic representation of the supramolecular polymers derived from
35 and
36. A representative SEM image of the fiber‐like assemblies also shown. The polymers could be disassembled in the presence of competitive guest molecules or anions. Source: Park et al. [110]. Figure reproduced by kind permission; © 2011 National Academy of Science.Figure 5.42 Schematic representation of the supramolecular 2 : 1 complex formed by γ‐CD and C
60 in water. Source: Based on Andersson et al. [114].Figure 5.43 Schematic
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