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      Supramolecular Polymers and Assemblies

      From Synthesis to Properties and Applications

       Ulrich S. Schubert George R. Newkome Andreas Winter

       Authors

       Prof. Ulrich S. Schubert

      Friedrich Schiller University Jena

      Laboratory for Organic and Macromolecular

      Chemistry (IOMC)

      Humboldtstraße 10

      07743 Jena

      Germany

       Prof. George R. Newkome

      Florida Atlantic University

      Center for Molecular Biology and Biotechnology

      Jupiter Campus, 5353 Parkside Drive, RF17/207

      Jupiter, FL 33458

      United States

       Dr. Andreas Winter

      Friedrich Schiller University Jena

      Laboratory for Organic and Macromolecular

      Chemistry (IOMC)

      Humboldtstraße 10

      07743 Jena

      Germany

       Cover

      Cover Image: © Sebestyen Balint/Shutterstock

      All books published by Wiley‐VCH are carefully produced. Nevertheless, authors, editors, and publisher do not warrant the information contained in these books, including this book, to be free of errors. Readers are advised to keep in mind that statements, data, illustrations, procedural details or other items may inadvertently be inaccurate.

       Library of Congress Card No.:

      applied for

       British Library Cataloguing‐in‐Publication Data

      A catalogue record for this book is available from the British Library.

       Bibliographic information published by the Deutsche Nationalbibliothek

      The Deutsche Nationalbibliothek lists this publication in the Deutsche Nationalbibliografie; detailed bibliographic data are available on the Internet at <http://dnb.d-nb.de>.

      © 2021 WILEY‐VCH GmbH, Boschstr. 12, 69469 Weinheim, Germany.

      All rights reserved (including those of translation into other languages). No part of this book may be reproduced in any form – by photoprinting, microfilm, or any other means – nor transmitted or translated into a machine language without written permission from the publishers. Registered names, trademarks, etc. used in this book, even when not specifically marked as such, are not to be considered unprotected by law.

      Print ISBN: 978‐3‐527‐33356‐1

      ePDF ISBN: 978‐3‐527‐83241‐5

      ePub ISBN: 978‐3‐527‐83240‐8

      oBook ISBN: 978‐3‐527‐68532‐5

       Printing and Binding

      Printed on acid‐free paper

      10 9 8 7 6 5 4 3 2 1

      There is a long history of the use of both naturally occurring polymers and synthetic polymers culminating in our current deep understanding of supramolecular polymers. In the 1500s, British explorers discovered that Mayan children were playing with rubber balls made from local trees and, 150 years ago, the first synthetic polymer was made by Wesley Hyatt. He treated cellulose with camphor to create a synthetic ivory to meet the needs of the then rapidly growing billiard enterprise. This year, synthetic polymer chemistry celebrates its 100th birthday, marked by when Hermann Staudinger published his then highly controversial proposal that polymers are indeed long chains, which are formed from repeating molecular units by covalent bonds. Throughout the last century, polymer chemistry has evolved tremendously not only with respect to the design and synthesis of tailor‐made architectures but also concerning the wide range of utilitarian applications to be found in our daily lives. By the 1970s, the use of polymer/plastic surpassed

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