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12.4Multi-component diffusion

       12.4.1Prigogine’s theorem

       12.4.2Diffusion in the solvent frame of reference

       12.4.3Other frames of reference

       12.4.4An example: Kinetic demixing of oxides

       12.5A relation between the heats of transfer and the enthalpy

       13A non-isothermal concentration cell

       13.1The homogeneous phases

       13.1.1Entropy production and flux equations for the anode

       13.1.2Position-dependent transport coefficients

       13.1.3The profiles of the homogeneous anode

       13.1.4Contributions from the cathode

       13.1.5The electrolyte contribution

       13.2Surface contributions

       13.2.1The anode surface

       13.2.2The cathode surface

       13.3The thermoelectric potential

       14The transported entropy

       14.1The Seebeck coefficient of cell a

       14.2The transported entropy of Pb²⁺ in cell a

       14.3The transported entropy of the cation in cell b

       14.4The transported entropy of the ions cell c

       14.5Transformation properties

       14.6Concluding comments

       15Adiabatic electrode reactions

       15.1The homogeneous phases

       15.1.1The silver phases

       15.1.2The silver chloride phases

       15.1.3The electrolyte

       15.2The interfaces

       15.2.1The silver–silver chloride interfaces

       15.2.2The silver chloride–electrolyte interfaces

       15.3Temperature and electric potential profiles

       16The liquid junction potential

       16.1The flux equations for the electrolyte

       16.2The liquid junction potential

       16.3Liquid junction potential calculations compared

       16.4Concluding comments

       17The formation cell

       17.1The isothermal cell

       17.1.1The electromotive force

       17.1.2The transference coefficient of the salt in the electrolyte

       17.1.3An electrolyte with a salt concentration gradient

       17.1.4The Planck potential derived from ionic fluxes and forces

       17.2A non-isothermal cell with a non-uniform electrolyte

       17.2.1The homogeneous anode phase

       17.2.2The electrolyte

       17.2.3The surface of the anode

       17.2.4The homogeneous phases and the surface of the cathode

       17.2.5The cell potential

       17.3Concluding comments

       18Power from regular and thermal osmosis

       18.1The potential work of a salt power plant

       18.2The membrane as a barrier to transport of heat and mass

       18.3Membrane transport of heat and mass

       18.4Osmosis

      

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