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4.5 (a) Diagram of the reaction cavity: (left) diagram around the N‐met...Figure 4.6 Transmission electron microscope (TEM) images of (a) tAlMCM‐41 an...Figure 4.7 (a) Synthetic procedure of CNC–(H₂P) _n . (b) TEM image of CNC–(H₂P) _n .Figure 4.8 (a) Transient absorption spectra of (a) CNC–(H₂P) _n taken at 20 and ...

      5 Chapter 5Figure 5.1 (a) Proposed complex formation. (b) UV–vis absorption titration of ...Figure 5.2 Transient absorption spectra of C8 and Py, in a 1 : 1 ratio at 5.0 ...Figure 5.3 Crystal structure of H₄DPP(FcCOO)₂ viewed from different directions...Figure 5.4 (a) Absorption spectral changes observed over the course of a titra...Figure 5.5 Driving force dependence of log k _ET (•) or k _BET (♦) for intrasupram...Figure 5.6 Dependence of ln k _ET on distance for intrasupramolecular electron t...Scheme 5.1 Supramolecular complex formation and photoinduced charge separation...Figure 5.7 UV–vis spectra of H₂TPPS⁴⁻ (2.0 × 10⁻⁶ M) in the presen...Figure 5.8 (a) Transient absorption spectra of H₂TPPS⁴⁻ (2.5 × 10⁻⁵...Figure 5.9 EPR spectra of (a) (ZnTPPS⁴⁻)^·+–Li⁺@C₆₀ ^·−...Figure 5.10 Formation of supramolecular porphyrin complexes, 1‐M⁴⁻/(2‐ZnFigure 5.11 X‐ray crystal structure of the supramolecular complex 1‐Zn^4– Figure 5.12 Chemical structure of Ni₂‐CPD_Py.Figure 5.13 Crystal structures of tubular assemblies of C₆₀⊂Ni₂‐CPD_Py. Hydroge...Figure 5.14 Supramolecular formation and photoinduced charge separation betwee...Figure 5.15 (a) Transient absorption spectra of Ni₂‐CPD_Py(OC₆) with Li⁺@C₆...Scheme 5.2 Energy diagram for Li⁺@C₆₀⊂Ni₂‐CPD_Py(OC₆); broken arrow: minor ...Figure 5.16 A porphyrin tripod and the reference dimer and monomer.Scheme 5.3 Formation of a supramolecular complex between TPZn₃ and PyC₆₀.Figure 5.17 (a) UV–vis spectral changes upon addition of PyC₆₀ (0–48 μM) to a Figure 5.18 Differential transient absorption spectra of (a) TPZn₃ (7.0 × 10^–6...Scheme 5.4 Energy diagram for photodynamics of (a) TPZn₃ and (b) MPZn in the p...Scheme 5.5 Photoinduced electron transfer in a π‐complex between a free base c...Figure 5.19 (a) Optimized structure of H₄DPOx–AcH⁺ by DFT calculation. (b)...Scheme 5.6 Energy diagram of photoinduced electron transfer of the H₄DPOx–AcH⁺...Figure 5.20 (a) Plot of ln(k _BET T ^1/2) vs. T ⁻¹ for the intramolecular BET ...Figure 5.21 Marcus driving force (−ΔG _ET) dependence of the ET rate constants (...Figure 5.22 (a) Supramolecular nanohybrids of porphyrin–peptide hexadecamer [P...Figure 5.23 (a) Spectroscopic changes observed when TTF‐C4P (30 μM) is treated...Figure 5.24 (a) Single crystal X‐ray structure of the supramolecular donor–acc...Scheme 5.7 Chemical structures of TTF‐C4P and BIQ²⁺ salts, and their propo...Scheme 5.8 Ion‐mediated electron‐transfer reactions of a supramolecule between...Figure 5.25 (a) Near‐IR absorption spectral change in Cl⁻‐promoted elect...Figure 5.26 (a) EPR spectrum of the products of electron transfer from TTF‐C4P...Figure 5.27 Single crystal X‐ray structure of the product of electron transfer...Figure 5.28 Change in absorbance at 1035 nm seen upon the addition of increasi...Figure 5.29 A supramolecular complex between a zinc porphyrin dendrimer [D(ZnP...Figure 5.30 (a) Transient absorption spectra of D(ZnP)₁₆ (2.3 × 10⁻⁵ M) ...Figure 5.31 (a) Insertion of C₆₀ between the porphyrin rings of H₂PC15MPC and ...Figure 5.32 Illustration of the preparation of the OTE/SnO₂/(H₂PC15MPC+C₆₀) _m e...Figure 5.33 (A) Photocurrent action spectra of OTE/SnO₂/(H₂PCnMPC+C₆₀) _m electr...Figure 5.34 Supramolecular organization between porphyrins and fullerenes with...Figure 5.35 (A) The photocurrent action spectra (IPCE vs. wavelength) of (a) (...Scheme 5.9 Schematic illustration of photocurrent generation mechanism of OTE/...Figure 5.36 Porphyrin dendrimers employed for construction of supramolecular s...Figure 5.37 TEM images of (a) Li⁺@C₆₀/ZnTPPS⁴⁻ and (b) Li⁺@C₆₀/HFigure 5.38 Schematic image of photoelectrochemical cell of OTE/SnO₂/MTPPS⁴⁻...Figure 5.39 Photocurrent action spectra of OTE/SnO₂/(ZnTPPS⁴⁻/Li⁺@C₆...

      6 Chapter 6Scheme 6.1 Energy diagram and photodynamics of a zinc porphyrin–naphthalenedii...Scheme 6.2 Photodynamics of a ferrocene–anthraquinone dyad (Fc–AQ) (a) in the ...Figure 6.1 Fluorescence responses (I/I ₀ at 610 nm) of ZnP–CONH–Q a...

      7 Chapter 7Scheme 7.1 Photocatalytic reaction of an electron donor (D) and an acceptor (A...Scheme 7.2 Photocatalytic oxygenation of anthracene with O₂ using Acr⁺–Mes...Scheme 7.3 Photocatalytic oxygenation of AnO₂ to anthraquinone with Acr^{+ ·}...Scheme 7.4 Photocatalytic [2 + 2] cycloaddition of O₂ to tetraphenylethylene (...Scheme 7.5 Photocatalytic cis–trans isomerization of stilbene with Acr⁺–Me...Scheme 7.6 Reaction scheme of photocatalytic oxygenation of p‐xylene and forma...Scheme 7.7 Photocatalytic mechanism of oxygenation of toluene derivatives (R‐CScheme 7.8 Photocatalytic mechanism of oxygenation of cyclohexane with Acr⁺...Scheme 7.9 Photocatalytic mechanism of bromination of aromatic compounds with ...Scheme 7.10 Photocatalytic dimerization of 9,10‐dimethylanthracene with Acr⁺...Figure 7.1 (a) Transient absorption spectra in PhCN observed in photoinduced E...Scheme 7.11 Photocatalytic oligomerization of C₆₀ with Acr⁺–Mes.Scheme 7.12 Photocatalytic DNA cleavage with Acr⁺–Mes.Figure 7.2 Agarose gel electrophoresis of photoinduced cleavage of supercoiled...Scheme 7.13 Photocatalytic cycle for intramolecular anti‐Markovnikov hydroethe...Scheme 7.14 Photocatalytic cycle of intermolecular cycloaddition between β‐met...Scheme 7.15 Photocatalytic cycle of anti‐Markovnikov alkene hydroacetoxylation...Scheme 7.16 Photocatalytic cycle of trifluoromethylation of alkenes.Figure 7.3 Time dependence of hydrogen evolution under steady‐state irradiatio...Scheme 7.17 Mechanism of photoinduced reduction of Acr⁺–Mes with

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