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Liquid Crystals. Iam-Choon Khoo
Читать онлайн.Название Liquid Crystals
Год выпуска 0
isbn 9781119705796
Автор произведения Iam-Choon Khoo
Издательство John Wiley & Sons Limited
Although individual molecules of nematic liquid crystal (NLC), cholesteric liquid crystal (CLC), and blue‐phase liquid crystal (BPLC) may be polar, i.e. carry a permanent dipole, they tend to self‐assemble themselves in such a manner that bulk liquid crystals are centrosymmetric, cf. Figure 1.12; their physical properties are the same in the
Cholesteric liquid crystals, often also called chiral nematic liquid crystals, resemble nematic liquid crystals except that the molecules assembled in a helical manner, as depicted in Figure 1.11. This property results from the addition of chiral agents to nematic constituents in the starting mixture. Owing to the spatially (helical) varying refractive index, CLCs possess special optical properties such as photonic bandgaps for transmission of circularly polarized lights. More details on CLC as well as cholesteric BPLCs obtained by increasing the concentration of the chiral constituent [10] in the starting mixture are presented in Chapter 4.
Figure 1.11. Self‐organization of the rod‐shaped LC molecules via local and long‐range order giving rise to various ordered phases of liquid crystal.
Figure 1.12. Arrangement of dipoles in the centrosymmetric bulk crystal such as nematics.
Smectic liquid crystals, unlike nematics, possess positional order; that is, the position of the molecules is correlated in some ordered pattern. We discuss here three representative ones: smectic‐A, smectic‐C, and smectic‐C* (ferroelectrics) due to their relevance to optical and photonic studies/applications noting that many other subphases of smectics such as smectic G, H, I, F…Q with different molecular arrangement and orders have been identified.
Figure 1.13. Molecular arrangements of liquid crystals: (a) smectic‐A; (b) smectic‐C; (c) smectic‐C* or ferroelectric; (d) unwound smectic‐C*.
Figure 1.13a depicts the layered structure of a smectic‐A liquid crystal. In each layer, the molecules are positionally random but directionally ordered, with their long axis normal to the plane of the layer. Similar to nematics, smectic‐A liquid crystals are optically uniaxial; that is, there is a rotational symmetry around the director axis.
The smectic‐C phase is different from the smectic‐A phase in that the material is optically biaxial, and the molecular arrangement is such that the long axis is tilted away from the layer normal
In smectic‐C* liquid crystals, as depicted in Figure 1.13c, the director axis
Smectic‐C* liquid crystals are interesting in one important aspect; namely, they comprise a system that permits, by the symmetry principle, the existence of spontaneous electric polarization. This can be explained simply in the following way. The spontaneous electric polarization
By convention,