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Figure 1.17 Beta emissions (both β^– and β⁺) are ejected from the nucleus with energies between 0 and their maximum possible energy (E_βmax). The average energy () is equal to approximately one third of the maximum energy.

      Electron capture:

Through a process that competes with positron decay, a nucleus can combine with one of its inner orbital electrons to achieve the net effect of converting one of the protons in the nucleus into a neutron (Figure 1.18). An outer‐shell electron then fills the vacancy in the inner shell left by the captured electron. The energy lost by the “fall” of the outer‐shell electron to the inner shell isemitted as an X‐ray.

Figure 1.18 Electron capture.

       Appropriate numbers of nucleons, but too much energy

       Isomeric transition:

      Following alpha and beta decay and electron capture, the nucleus has a more favorable physical configuration of nucleons but usually contains an excess of energy. The nucleus is said to be in an excited state when the energy of the nucleus is greater than its resting level. This excess energy is shed by isomeric transition. This may occur by either or both of two competing reactions: gamma emission or internal conversion. Most isomeric transitions occur as a combination of these two reactions.

      Gamma emission:

In this process, excess nuclear energy is emitted as a gamma ray (Figure 1.19). The name gamma was given to this radiation, before its physical nature was understood, because it was the third (alpha, beta, gamma) type of radiation discovered. A gamma ray is a photon (energy) emitted by an excited nucleus. Despite its unique name, it cannot be distinguished from photons of the same energy from different sources, for example X‐rays.

      Internal conversion:

The excited nucleus can transfer its excess energy to an orbital electron (generally an inner‐shell electron) causing the electron to be ejected from the atom. This can only occur if the excess energy is greater than the binding energy of the electron. This electron is called a conversion electron. The resulting inner orbital vacancy is rapidly filled with an outer‐shell electron (as the atom assumes a more stable state, inner orbitals are filled before outer orbitals). The energy released as a result of the “fall” of an outer‐shell electron to an inner shell is emitted as an X‐ray (Figure 1.20a) or as a free electron, an Auger electron (Figure 1.20b). The emitted X‐ray is called a characteristic X‐ray because its energy always equals the difference in binding energies between the electron shells.

      Decay notation

Decay from an unstable parent nuclide to a more stable daughter nuclide can occur in a series of steps, with the production of particles and photons characteristic of each step. A standard notation is used to describe these steps (Figure 1.21). The uppermost level of the schematic is the state with the greatest energy. As the nuclide decays by losing energy and/or particles, lower horizontal levels represent states of relatively lower energy. Directional arrows from one level to the next indicate the type of decay. By convention, an oblique line angled downward and to the left indicates electron capture; downward and to the right, beta emission; and a vertical arrow, an isomeric transition. The dogleg is used for positron emission. A dogleg with a “Z” denotes alpha decay. Notice that a pathway ending to the left, as in electron capture or positron emission, corresponds to a decrease in atomic number. On the other hand, a line ending to the right, as in beta emission, corresponds to an increase in atomic number.

Figure 1.19 Isomeric transition. Excess nuclear energy is carried off as a gamma ray.

Figure 1.20 Internal conversion. As an alternative to gamma emission, it can lead to emission of either an X‐ray (a) or an Auger electron (b).

Figure 1.22 depicts specific decay schemes for ^99mTc, ¹¹¹In, ¹³¹I, and ²²⁶Ra (this is not the isotope used for treatment in nuclear medicine, ²²³Ra, which will be discussed in detail in Chapter 18). The “m” in ^99mTc stands for metastable, which refers to an excited nucleus with an appreciable lifetime (>10^–12 seconds) prior to undergoing isomeric transition.

      Half‐life

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