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The History of Chemistry (Vol.1&2). Thomas Thomson
Читать онлайн.Название The History of Chemistry (Vol.1&2)
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isbn 4064066399887
Автор произведения Thomas Thomson
Жанр Математика
Издательство Bookwire
4. Sal ammoniac was known to Geber, and seems to have been quite common in his time. There is no evidence that it was known to the Greeks or Romans, as neither Dioscorides nor Pliny make any allusion to it. The word in old books is sometimes sal armoniac, sometimes sal ammoniac. It is supposed to have been brought originally from the neighbourhood of the temple of Jupiter Ammon: but had this been the case, and had it occurred native, it could scarcely have been unknown to the Romans, under whose dominions that part of Africa fell. In the writings of the alchymists, sal ammoniac is mentioned under the following whimsical names:
Anima sensibilis,
Aqua duorum fratrum ex sorore,
Aquila,
Lapis aquilinis,
Cancer,
Lapis angeli conjungentis,
Sal lapidum,
Sal alocoph.
Geber not only knew sal ammoniac, but he was aware of its volatility; and gives various processes for subliming it, and uses it frequently to promote the sublimation of other bodies, as of oxides of iron and copper. He gives also a method of procuring it from urine, a liquid which, when allowed to run into putrefaction, is known to yield it in abundance. Sal ammoniac was much used by Geber, in his various processes to bring the inferior metals to a state of greater perfection. By adding it or common salt to aqua fortis, he was enabled to dissolve gold, which certainly could not be accomplished in the time of Dioscorides or Pliny. The description, indeed, of Geber’s process for dissolving gold is left on purpose in a defective state; but an attentive reader will find no great difficulty in supplying the defects, and thus understanding the whole of the process.
5. Alum, precisely the same as the alum of the moderns, was familiarly known to Geber, and employed by him in his processes. The manufacture of this salt, therefore, had been discovered between the time when Pliny composed his Natural History and the eighth century, when Geber wrote; unless we admit that the mode of making it had been known to the Tyrian dyers, but that they had kept the secret so well, that no suspicion of its existence was entertained by the Greeks and Romans. That they employed alumina as a mordant in some of their dyes, is evident; but there is no proof whatever that alum, in the modern sense of the word, was known to them.
Geber mentions three alums which he was in the habit of using; namely, icy alum, or Rocca alum; Jamenous alum, or alum of Jameni, and feather alum. Rocca, or Edessa, in Syria, is admitted to have been the place where the first manufactory of alum was established; but at what time, or by whom, is quite unknown: we know only that it must have been posterior to the commencement of the Christian era, and prior to the eighth century, when Geber wrote. Jameni must have been another locality where, at the time of Geber, a manufactory of alum existed. Feather alum was undoubtedly one of the native impure varieties of alum, known to the Greeks and Romans. Geber was in the habit of distilling alum by a strong heat, and of preserving the water which came over as a valuable menstruum. If alum be exposed to a red heat in glass vessels, it will give out a portion of sulphuric acid: hence water distilled from alum by Geber was probably a weak solution of sulphuric acid, which would undoubtedly act powerfully as a solvent of iron, and of the alkaline carbonates. It was probably in this way that he used it.
6. Sulphate of iron or copperas, as it is called (cuperosa), in the state of a crystalline salt, was well known to Geber, and appears in his time to have been manufactured.
7. Baurach, or borax, is mentioned by him, but without any description by which we can know whether or not it was our borax: the probability is that it was. Both glass and borax were used by him when the oxides of metals were reduced by him to the metallic state.
8. Vinegar was purified by him by distilling it over, and it was used as a solvent in many of his processes.
9. Nitric acid was known to him by the name of dissolving water. He prepared it by putting into an alembic one pound of sulphate of iron of Cyprus, half a pound of saltpetre, and a quarter of a pound of alum of Jameni: this mixture was distilled till every thing liquid was driven over. He mentions the red fumes which make their appearance in the alembic during the process.122 This process, though not an economical one, would certainly yield nitric acid; and it is remarkable, because it is here that we find the first hint of the knowledge of chemists of this most important acid, without which many chemical processes of the utmost importance could not be performed at all.
10. This acid, thus prepared, he made use of to dissolve silver: the solution was concentrated till the nitrate of silver was obtained by him in a crystallized state. This process is thus described by him: “Dissolve silver calcined in solutive water (nitric acid), as before; which being done, coct it in a phial with a long neck, the orifice of which must be left unstopped, for one day only, until a third part of the water be consumed. This being effected, set it with its vessel in a cold place, and then it is converted into small fusible stones, like crystal.”123
11. He was in the habit also of dissolving sal ammoniac in this nitric acid, and employing the solution, which was the aqua regia of the old chemists, to dissolve gold.124 He assures us that this aqua regia would dissolve likewise sulphur and silver. The latter assertion is erroneous. But sulphur is easily converted into sulphuric acid by the action of aqua regia, and of course it disappears or dissolves.
12. Corrosive sublimate is likewise described by Geber in a very intelligible manner. His method of preparing it was as follows: “Take of mercury one pound, of dried sulphate of iron two pounds, of alum calcined one pound, of common salt half a pound, and of saltpetre a quarter of a pound: incorporate altogether by trituration and sublime; gather the white, dense, and ponderous portions which shall be found about the sides of the vessel. If in the first sublimation you find it turbid or unclean (which may happen by reason of your own negligence), sublime a second time with the same fuses.”125 Still more minute directions are given in other parts of the work: we have even some imperfect account of the properties of corrosive sublimate.
13. Corrosive sublimate is not the only preparation of mercury mentioned by Geber. He informs us that when mercury is combined with sulphur it assumes a red colour, and becomes cinnabar.126 He describes the affinities of mercury for the different metals. It adheres easily to three metals; namely, lead, tin, and gold; to silver with more difficulty. To copper with still more difficulty than to silver; but to iron it unites in nowise unless by artifice.127 This is a tolerably accurate account of the matter. He says, that mercury is the heaviest body in nature except gold, which is the only metal that will sink in it.128 Now this was true, applied to all the substances known when Geber lived.
He gives an account of the method of forming the peroxide of mercury by heat; that variety of it formerly distinguished by the name of red precipitati per se. “Mercury,” he says, “is also coagulated by long and constant retention in fire, in a glass vessel with a very long neck and round belly; the orifice of the neck being kept open, that the humidity may vanish thereby.”129 He gives another process for preparing this oxide, possible, perhaps, though certainly requiring very cautious regulation of the fire. “Take,” says he, “of mercury one pound, of vitriol (sulphate of iron) rubified two pounds, and of saltpetre one pound. Mortify the mercury with these, and then sublime it from rock alum and saltpetre in equal weights.”130
14. Geber was acquainted with several of the compounds of metals with sulphur. He remarks that sulphur when fused with metals increases their weight.131 Copper combined with sulphur becomes yellow, and mercury red.132 He knew the method of dissolving sulphur in caustic potash, and again precipitating it by the addition of an acid. His process is as follows: “Grind clear and gummose sulphur to a most subtile powder, which boil in a lixivium made of ashes of heartsease and quicklime, gathering from off the surface its oleaginous combustibility, until it be discerned to be clear. This being done, stir the whole with a stick, and then warily take off that which passeth out with the lixivium, leaving the more gross parts in the bottom. Permit that extract to cool a little, and upon it pour a fourth part of its own quantity of distilled vinegar, and then will the whole suddenly be congealed as milk. Remove as much of the clear